LBNL Report Number
The properties of VO2, thermochromic coatings were investigated for application to building windows. The solar transmittance of VO2 decreases above a certain temperature, blocking excess solar gain. Films were deposited on glass by reactive magnetron sputtering, but stoichiometric compositions have not yet been achieved. The composition and structure of these films have been determined by Auger spectroscopy and x-ray diffraction. Optical properties were measured by photometric and ellipsometric methods. Using this optical data, composite coatings were designed having improved optical characteristics. The high-temperature metallic state of VO2 was not found to be suitable as a static low-emissivity coating. When this VO2, is used as a thermochromic coating, however, its moderately low-emissivity would contribute to energy savings. The ratio of solar transmittance between the high-temperature and low-temperature states increases with decreasing average transmittance. Higher values of this ratio might be obtained by proper choice of additional coating layers.